Using the Pimoroni Blinkt! is easy. First, make sure your Raspberry Pi has a 40 - pin (2x20) GPIO. Then, gently snap the Blinkt! on top of your Pi, making sure the curved parts match the corners of the Pi. Next, head to the GitHub repository provided by Pimoroni. There you can find the Blinkt! software bundled with examples in a Python module. Install the software, and you're ready to start playing with colors. To set the color of each LED, you can follow the examples in the module. You can create different effects like gradients or pulsing lights. When it comes to maintenance, keep the Blinkt! clean and free from dust. Avoid using abrasive materials to clean it. And always remember to plug it in the correct way to prevent any damage.